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The time zone setting is applied to Admission Times of jobs in the workflow:
Timed Orders from Schedules
When using JS7 - Schedules to create orders then the schedule is specified with a time zone that by default is populated from the user profile's time zone.
Ad hoc Orders from User Intervention
When manually adding orders to a workflow for a later date then the time zone is specified like this:
Note: If the option "Now" is used then the order starts immediately independently from the user's time zone setting.
Daily Plan Service
The Daily Plan Settings consider a time zone for the start of the 24 hours period of the Daily Plan and for the point in time when the Daily Plan is calculated, see JS7 - Daily Plan Service.
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